Two movements that have given me the best chest development are: Incline smith, and Bench (both freebar and smith). Just progressively getting stronger at these have made my chest grow.
Dante's pec stretching after an exercise has done wonders too.
Might be different for someone with dominating arms who can press a ton without great development, but it's usually rare. All those flys, and "volumizing" exercise have done absolutely nothing for me.
Just my 2 cents.
Have you ever tried guillotine press?
I have seen the best growth with heavy incline first.
When and how many times do any of you train chest, and who works upper chest first?